Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases
نویسندگان
چکیده
The efficient synthesis of hydrosilanes by catalytic ydrogenolysis chlorosilanes is described, using an Iridum (III) pincer catalyst. A careful selection a nitrogen base (incl. sterically hindered guanidines and phosphazenes) can unlock the preparation of Me3SiH, Et3SiH Me2SiHCl in high yield (up to 98%), directly from their corresponding chlorosilanes.
منابع مشابه
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ژورنال
عنوان ژورنال: ACS Catalysis
سال: 2021
ISSN: ['2155-5435']
DOI: https://doi.org/10.1021/acscatal.1c01515